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A Visible Light-Mediated Radical Smiles Rearrangement and its Application to the Synthesis of a Difluorospirocyclic ORL-1 Antagonist()
A visible light-mediated radical Smiles rearrangement has been developed to address the challenging synthesis of a gem-difluoro group present in an opioid receptor-like 1 (ORL-1) antagonist currently in development. This method led to the direct and efficient introduction of the difluoroethanol moti...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4725294/ https://ncbi.nlm.nih.gov/pubmed/26474077 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201507369 |
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