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Predicting the structure and vibrational frequencies of ethylene using harmonic and anharmonic approaches at the Kohn–Sham complete basis set limit

In this work, regular convergence patterns of the structural, harmonic, and VPT2-calculated anharmonic vibrational parameters of ethylene towards the Kohn–Sham complete basis set (KS CBS) limit are demonstrated for the first time. The performance of the VPT2 scheme implemented using density function...

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Publicat a:J Mol Model
Autors principals: Buczek, Aneta, Kupka, Teobald, Broda, Małgorzata A., Żyła, Adriana
Format: Artigo
Idioma:Inglês
Publicat: Springer Berlin Heidelberg 2016
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4723629/
https://ncbi.nlm.nih.gov/pubmed/26800989
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00894-015-2902-z
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