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Conversion of Aldehyde to Alkane by a Peroxoiron(III) Complex: A Functional Model for the Cyanobacterial Aldehyde-Deformylating Oxygenase

Cyanobacterial aldehyde-deformylating oxygenase (cADO) converts long-chain fatty aldehydes to alkanes via a proposed diferric-peroxo intermediate that carries out the oxidative deformylation of the substrate. Herein, we report that the synthetic iron(III)-peroxo complex [Fe(III)(η(2)−O(2))(TMC)](+)...

詳細記述

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書誌詳細
出版年:J Am Chem Soc
主要な著者: Shokri, Alireza, Que, Lawrence
フォーマット: Artigo
言語:Inglês
出版事項: 2015
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC4722334/
https://ncbi.nlm.nih.gov/pubmed/26030345
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b01053
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