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The crystal structures of tetrakis(μ-n-butyrato-κ(2) O:O′)bis[bromidorhenium(III)] and tetrakis(μ-n-butyrato-κ(2) O:O′)bis[chloridorhenium(III)] acetonitrile disolvate
The title complexes, [Re(2)Br(2)(O(2)CC(3)H(7))(4)], (1), and [Re(2)(O(2)CC(3)H(7))(4)Cl(2)]·2CH(3)CN, (2), both exhibit paddlewheel structures with four carboxylate ligands bridging two Re(III) atoms. The Re—Re distances are 2.2325 (2) and 2.2299 (3) Å, indicating quadruple bonds between the Re(II...
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| izdano v: | Acta Crystallogr E Crystallogr Commun |
|---|---|
| Main Authors: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
International Union of Crystallography
2015
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4719818/ https://ncbi.nlm.nih.gov/pubmed/26870409 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989015020563 |
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