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Pb, Sr and Ba calix[6]arene hexacarboxylic acid octahedral complexation: a dramatic effect of dealkylation

Calix[6]arene hexacarboxylic acid binds instantly and with low symmetry to Pb, Sr and Ba. Later a highly symmetric up-down alternating conformation emerges. The solution structures are identical to their p-tert-butylcalix[6]arene hexacarboxylic acid counterparts. With either receptor an octahedral c...

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Pubblicato in:Supramol Chem
Autori principali: Adhikari, Birendra Babu, To, Cuong-Alexander, Iwasawa, Tetsuo, Schramm, Michael P.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2015
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4704459/
https://ncbi.nlm.nih.gov/pubmed/26752941
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1080/10610278.2015.1078898
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