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Hydrogen-Bonding Interactions Trigger a Spin-Flip in Iron(III) Porphyrin Complexes**

A key step in cytochrome P450 catalysis includes the spin-state crossing from low spin to high spin upon substrate binding and subsequent reduction of the heme. Clearly, a weak perturbation in P450 enzymes triggers a spin-state crossing. However, the origin of the process whereby enzymes reorganize...

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Dades bibliogràfiques
Publicat a:Angew Chem Int Ed Engl
Autors principals: Sahoo, Dipankar, Quesne, Matthew G, de Visser, Sam P, Rath, Sankar Prasad
Format: Artigo
Idioma:Inglês
Publicat: WILEY-VCH Verlag 2015
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4687417/
https://ncbi.nlm.nih.gov/pubmed/25645603
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201411399
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