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Six-Coordinate Zinc Porphyrins for Template-Directed Synthesis of Spiro-Fused Nanorings
[Image: see text] Five-coordinate geometry is the standard binding mode of zinc porphyrins with pyridine ligands. Here we show that pseudo-octahedral six-coordinate zinc porphyrin complexes can also be formed in solution, by taking advantage of the chelate effect. UV–vis–NIR titrations indicate that...
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| Publicado no: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2015
|
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4686216/ https://ncbi.nlm.nih.gov/pubmed/26536147 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b10126 |
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