Six-Coordinate Zinc Porphyrins for Template-Directed Synthesis of Spiro-Fused Nanorings

[Image: see text] Five-coordinate geometry is the standard binding mode of zinc porphyrins with pyridine ligands. Here we show that pseudo-octahedral six-coordinate zinc porphyrin complexes can also be formed in solution, by taking advantage of the chelate effect. UV–vis–NIR titrations indicate that...

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Publicat a:J Am Chem Soc
Autors principals: Favereau, Ludovic, Cnossen, Arjen, Kelber, Julien B., Gong, Juliane Q., Oetterli, René M., Cremers, Jonathan, Herz, Laura M., Anderson, Harry L.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2015
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4686216/
https://ncbi.nlm.nih.gov/pubmed/26536147
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b10126
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