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Iron complexes of tetramine ligands catalyse allylic hydroxyamination via a nitroso–ene mechanism

Iron(II) complexes of the tetradentate amines tris(2-pyridylmethyl)amine (TPA) and N,N′-bis(2-pyridylmethyl)-N,N′-dimethylethane-1,2-diamine (BPMEN) are established catalysts of C–O bond formation, oxidising hydrocarbon substrates via hydroxylation, epoxidation and dihydroxylation pathways. Herein w...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Porter, David, Poon, Belinda M-L, Rutledge, Peter J
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4685922/
https://ncbi.nlm.nih.gov/pubmed/26734101
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.11.275
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