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Friedel–Crafts-type reaction of pyrene with diethyl 1-(isothiocyanato)alkylphosphonates. Efficient synthesis of highly fluorescent diethyl 1-(pyrene-1-carboxamido)alkylphosphonates and 1-(pyrene-1-carboxamido)methylphosphonic acid

Friedel–Crafts-type reaction of pyrene with diethyl 1-(isothiocyanato)alkylphosphonates promoted by trifluoromethanosulfonic acid afforded diethyl 1-(pyrene-1-carbothioamido)alkylphosphonates in 83–94% yield. These compounds were transformed, in 87–94% yield, into the corresponding diethyl 1-(pyrene...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Wrona-Piotrowicz, Anna, Zakrzewski, Janusz, Gajda, Anna, Gajda, Tadeusz, Makal, Anna, Brosseau, Arnaud, Métivier, Rémi
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4685883/
https://ncbi.nlm.nih.gov/pubmed/26734093
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.11.266
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