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Absence of Stereodirecting Participation by 2-O-Alkoxycarbonylmethyl Ethers in 4,6-O-Benzylidene-Directed Mannosylation

The preparation of a series of mannopyranosyl donors carrying 2-O-(2-oxoalkyl) ethers and their use in glycosylation reactions is described. The formation of cyclic products with the simple 2-O-phenacyl ether and with the 2-O-(t-butoxycarbonylmethyl) ether establishes the stereoelectronic feasibilit...

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Pubblicato in:J Org Chem
Autori principali: Wen, Peng, Crich, David
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2015
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4684826/
https://ncbi.nlm.nih.gov/pubmed/26565923
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.5b02203
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