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Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis

Reaction between a β-diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH(3), an observable magnesium formyl species may be intercepted for the mild re...

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Xehetasun bibliografikoak
Argitaratua izan da:Angew Chem Int Ed Engl
Egile Nagusiak: Anker, Mathew D, Hill, Michael S, Lowe, John P, Mahon, Mary F
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: WILEY-VCH Verlag 2015
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC4678424/
https://ncbi.nlm.nih.gov/pubmed/26220407
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201505851
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