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The Fe–V Cofactor of Vanadium Nitrogenase Contains an Interstitial Carbon Atom
The first direct evidence is provided for the presence of an interstitial carbide in the Fe–V cofactor of Azotobacter vinelandii vanadium nitrogenase. As for our identification of the central carbide in the Fe–Mo cofactor, we employed Fe Kβ valence-to-core X-ray emission spectroscopy and density fun...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
WILEY-VCH Verlag
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4675075/ https://ncbi.nlm.nih.gov/pubmed/26376620 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201505930 |
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