Redox and Coordination Behavior of the Hexaphosphabenzene Ligand in [(Cp*Mo)(2)(μ,η(6):η(6)-P(6))] Towards the “Naked” Cations Cu(+), Ag(+), and Tl(+)

Although the cyclo-P(6) complex [(Cp*Mo)(2)(μ,η(6):η(6)-P(6))] (1) was reported 30 years ago, little is known about its chemistry. Herein, we report a high-yielding synthesis of 1, the complex 2, which contains an unprecedented cyclo-P(10) ligand, and the reactivity of 1 towards the “naked” cations...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Fleischmann, Martin, Dielmann, Fabian, Gregoriades, Laurence J, Peresypkina, Eugenia V, Virovets, Alexander V, Huber, Sebastian, Timoshkin, Alexey Y, Balázs, Gábor, Scheer, Manfred
Format: Artigo
Idioma:Inglês
Publicat: WILEY-VCH Verlag 2015
Matèries:
Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4675074/
https://ncbi.nlm.nih.gov/pubmed/26337857
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201506362
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