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Alkaline-Earth-Catalyzed Dehydrocoupling of Amines and Boranes

Dehydrocoupling reactions between the boranes HBpin and 9-borabicyclo[3.3.1]nonane and a range of amines and anilines ensue under very mild reaction conditions in the presence of a simple β-diketiminato magnesium n-butyl precatalyst. The facility of the reactions is suggested to be a function of the...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Liptrot, David J, Hill, Michael S, Mahon, Mary F, Wilson, Andrew S S
Natura: Artigo
Lingua:Inglês
Pubblicazione: WILEY-VCH Verlag 2015
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4674969/
https://ncbi.nlm.nih.gov/pubmed/26360523
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201505949
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