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Stabilization of Cu(I) for binding and calorimetric measurements in aqueous solution
Conditions have been developed for the comproportionation reaction of Cu(2+) and copper metal to prepare aqueous solutions of Cu(+) that are stabilized from disproportionation by MeCN and other Cu(+)-stabilizing ligands. These solutions were then used in ITC measurements to quantify the thermodynami...
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| Veröffentlicht in: | Dalton Trans |
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| Hauptverfasser: | , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2015
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4669220/ https://ncbi.nlm.nih.gov/pubmed/26327397 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5dt02689j |
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