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Preparation of 3-benzyloxy-2-pyridinone functional linkers: Tools for the synthesis of 3,2-hydroxypyridinone (HOPO) and HOPO/hydroxamic acid chelators

In contrast to 2,3-dihydroxypyridine, the 3-benzyloxy protected derivative, 2, undergoes facile alkylation at ambient temperatures with a variety of functionalized alkyl halides in good yields. This alkylation has been used to prepare a number of linkers that permit the attachment of 3,2-HOPO moieti...

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Publicat a:Tetrahedron
Autors principals: Gibson, Sarah, Fernando, Rasika, Jacobs, Hollie K., Gopalan, Aravamudan S.
Format: Artigo
Idioma:Inglês
Publicat: 2015
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4665106/
https://ncbi.nlm.nih.gov/pubmed/26640304
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2015.10.031
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