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Asymmetric 1,4-bis(ethynyl)bicyclo[2.2.2]octane rotators via monocarbinol functionalization. Ready access to polyrotors

Asymmetric rotators with a 1,4-bis(ethynyl)bicyclo[2.2.2]octane (BCO) core are needed for engineering crystalline arrays of functional molecular rotors. Their synthesis uses carbinol, 2-methyl-3-butyn-2-ol, as a protecting group because of its polar character and its ability to sustain orthogonal fu...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Lemouchi, Cyprien, Batail, Patrick
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4660993/
https://ncbi.nlm.nih.gov/pubmed/26664606
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.11.202
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