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Evidencing an inner-sphere mechanism for NHC-Au(I)-catalyzed carbene-transfer reactions from ethyl diazoacetate
Kinetic experiments based on the measurement of nitrogen evolution in the reaction of ethyl diazoacetate (N(2)CHCO(2)Et, EDA) and styrene or methanol catalyzed by the [IPrAu](+) core (IPr = 1,3-bis(diisopropylphenyl)imidazole-2-ylidene) have provided evidence that the transfer of the carbene group C...
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| Publicado no: | Beilstein J Org Chem |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4660976/ https://ncbi.nlm.nih.gov/pubmed/26664649 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.11.245 |
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