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Preparation of conjugated dienoates with Bestmann ylide: Towards the synthesis of zampanolide and dactylolide using a facile linchpin approach

Bestmann ylide [(triphenylphosphoranylidene)ketene] acts as a chemical linchpin that links nucleophilic entities, such as alcohols or amines, with carbonyl moieties to produce unsaturated esters and amides, respectively. In this work, the formation of α,β,γ,δ-unsaturated esters (dienoates) is achiev...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Wang, Jingjing, Ting, Samuel Z Y, Harvey, Joanne E
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4660958/
https://ncbi.nlm.nih.gov/pubmed/26664601
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.11.197
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