High-temperature in situ crystallographic observation of reversible gas sorption in impermeable organic cages

Crystallographic observation of adsorbed gas molecules is a highly difficult task due to their rapid motion. Here, we report the in situ single-crystal and synchrotron powder X-ray observations of reversible CO(2) sorption processes in an apparently nonporous organic crystal under varying pressures...

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Dettagli Bibliografici
Pubblicato in:Proc Natl Acad Sci U S A
Autori principali: Baek, Seung Bin, Moon, Dohyun, Graf, Robert, Cho, Woo Jong, Park, Sung Woo, Yoon, Tae-Ung, Cho, Seung Joo, Hwang, In-Chul, Bae, Youn-Sang, Spiess, Hans W., Lee, Hee Cheon, Kim, Kwang S.
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 2015
Soggetti:
Physical Sciences
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4655546/
https://ncbi.nlm.nih.gov/pubmed/26578758
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1504586112
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