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Cleavage of a C-C Bond in Cyclobutylanilines Enabled by Visible Light Photoredox Catalysis: Development of a New [4+2] Annulation Method

We report the first example of intermolecular [4+2] annulation of cyclobutylanilines with alkynes enabled by visible light photocatalysis. Monocyclic and bicyclic cyclobutylanilines successfully undergo the annulation with terminal and internal alkynes to generate a wide variety of amine-substituted...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Wang, Jiang, Zheng, Nan
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2015
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4653064/
https://ncbi.nlm.nih.gov/pubmed/26228259
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201504076
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