Reduction of Carbon Dioxide to Formate at Low Overpotential Using a Superbase Ionic Liquid

A new low-energy pathway is reported for the electrochemical reduction of CO(2) to formate and syngas at low overpotentials, utilizing a reactive ionic liquid as the solvent. The superbasic tetraalkyl phosphonium ionic liquid [P(66614)][124Triz] is able to chemisorb CO(2) through equimolar binding o...

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Bibliografiset tiedot
Julkaisussa:Angew Chem Int Ed Engl
Päätekijät: Hollingsworth, Nathan, Taylor, S F Rebecca, Galante, Miguel T, Jacquemin, Johan, Longo, Claudia, Holt, Katherine B, de Leeuw, Nora H, Hardacre, Christopher
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: WILEY-VCH Verlag 2015
Aiheet:
Communications
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC4648032/
https://ncbi.nlm.nih.gov/pubmed/26403938
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201507629
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