Total Synthesis of (+)-Rubriflordilactone A

Two enantioselective total syntheses of the nortriterpenoid natural product rubriflordilactone A are described, which use palladium- or cobalt-catalyzed cyclizations to form the CDE rings, and converge on a late-stage synthetic intermediate. These key processes are set up through the convergent coup...

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發表在:Angew Chem Int Ed Engl
Main Authors: Goh, Shermin S, Chaubet, Guilhem, Gockel, Birgit, Cordonnier, Marie-Caroline A, Baars, Hannah, Phillips, Andrew W, Anderson, Edward A
格式: Artigo
語言:Inglês
出版: WILEY-VCH Verlag 2015
主題:
Communications
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC4643188/
https://ncbi.nlm.nih.gov/pubmed/26337920
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201506366
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