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Facile Synthesis and Properties of 2-λ(5)-Phosphaquinolines and 2-λ(5)-Phosphaquinolin-2-ones()
Treatment of 2-ethynylanilines with P(OPh)(3) gives either 2,2-diphenoxy-2-λ(5)-phosphaquinolines or 2-phenoxy-2-λ(5)-phospha-quinolin-2-ones under transition metal-free conditions. This reaction offers unparalleled access to an underexplored heterocycle, which opens study of the fundamental nature...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4624000/ https://ncbi.nlm.nih.gov/pubmed/26361244 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201507696 |
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