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Boryl (Hetero)aryne Precursors as Versatile Arylation Reagents: Synthesis through C–H Activation and Orthogonal Reactivity

(Pinacolato)boryl ortho-silyl(hetero)aryl triflates are presented as a new class of building blocks for arylation. They demonstrate unique versatility by delivering boronate or (hetero)aryne reactivity chemoselectively in a broad range of transformations. This approach enables the unprecedented post...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Demory, Emilien, Devaraj, Karthik, Orthaber, Andreas, Gates, Paul J, Pilarski, Lukasz T
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4600243/
https://ncbi.nlm.nih.gov/pubmed/26270451
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201503152
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