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Phosphate Tether-Mediated Ring-Closing Metathesis for the Generation of Medium to Large, P-Stereogenic Bicyclo[n.3.1]phosphates

A phosphate tether-mediated ring-closing metathesis study towards the synthesis of P-stereogenic bicyclo[6.3.1]-, bicyclo[7.3.1]-, and bicyclo[8.3.1]phosphates is reported. This study demonstrates expanded utility of phosphate tether-mediated desymmetrization of C(2)-symmetric, 1,3-anti-diol dienes...

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Pubblicato in:Tetrahedron
Autori principali: Maitra, Soma, Markley, Jana L, Chegondi, Rambabu, Hanson, Paul R.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2015
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4584409/
https://ncbi.nlm.nih.gov/pubmed/26430283
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2015.06.016
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