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Configurationally stable, enantioenriched organometallic nucleophiles in stereospecific Pd-catalyzed cross-coupling reactions: an alternative approach to asymmetric synthesis

Several research groups have recently developed methods to employ configurationally stable, enantioenriched organometallic nucleophiles in stereospecific Pd-catalyzed cross-coupling reactions. By establishing the absolute configuration of a chiral alkyltin or alkylboron nucleophile prior to its use...

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Publicat a:Chem Sci
Autors principals: Wang, Chao-Yuan, Derosa, Joseph, Biscoe, Mark R.
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2015
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4571484/
https://ncbi.nlm.nih.gov/pubmed/26388985
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01710f
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