Crystal structure of bis­[μ-bis­(di­phenyl­phosphanyl)methane-κ(2) P:P′]digold(I) dichloride acetone monosolvate monohydrate

In the title complex salt, [Au(2){(C(6)H(5))(2)PCH(2)P(C(6)H(5))(2)}]Cl(2)·(CH(3))(2)C=O·H(2)O, the dication forms an eight-membered {—PCPAu}(2) ring with a transannular aurophilic inter­action [Au⋯Au = 2.9743 (2) Å]. The ring approximates a flattened boat conformation, with the two methyl­ene C ato...

Full beskrivning

Sparad:
Bibliografiska uppgifter
I publikationen:Acta Crystallogr E Crystallogr Commun
Huvudupphovsmän: Yeo, Chien Ing, Tan, Yee Seng, Tiekink, Edward R. T.
Materialtyp: Artigo
Språk:Inglês
Publicerad: International Union of Crystallography 2015
Ämnen:
Research Communications
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC4571361/
https://ncbi.nlm.nih.gov/pubmed/26396760
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989015013341
Taggar: Lägg till en tagg
Inga taggar, Lägg till första taggen!

Liknande verk