Electrochemically addressable trisradical rotaxanes organized within a metal–organic framework

The organization of trisradical rotaxanes within the channels of a Zr(6)-based metal–organic framework (NU-1000) has been achieved postsynthetically by solvent-assisted ligand incorporation. Robust Zr(IV)–carboxylate bonds are forged between the Zr clusters of NU-1000 and carboxylic acid groups of r...

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Veröffentlicht in:Proc Natl Acad Sci U S A
Hauptverfasser: McGonigal, Paul R., Deria, Pravas, Hod, Idan, Moghadam, Peyman Z., Avestro, Alyssa-Jennifer, Horwitz, Noah E., Gibbs-Hall, Ian C., Blackburn, Anthea K., Chen, Dongyang, Botros, Youssry Y., Wasielewski, Michael R., Snurr, Randall Q., Hupp, Joseph T., Farha, Omar K., Stoddart, J. Fraser
Format: Artigo
Sprache:Inglês
Veröffentlicht: National Academy of Sciences 2015
Schlagworte:
Physical Sciences
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4568662/
https://ncbi.nlm.nih.gov/pubmed/26283386
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1514485112
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