All-Carbon [3+3] Oxidative Annulations of 1,3-Enynes by Rhodium(III)-Catalyzed C–H Functionalization and 1,4-Migration**

1,3-Enynes containing allylic hydrogens cis to the alkyne function as three-carbon components in rhodium(III)-catalyzed, all-carbon [3+3] oxidative annulations to produce spirodialins. The proposed mechanism of these reactions involves the alkenyl-to-allyl 1,4-rhodium(III) migration.

Tallennettuna:
Bibliografiset tiedot
Julkaisussa:Angew Chem Int Ed Engl
Päätekijät: Burns, David J, Best, Daniel, Wieczysty, Martin D, Lam, Hon Wai
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: WILEY-VCH Verlag 2015
Aiheet:
Communications
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC4557058/
https://ncbi.nlm.nih.gov/pubmed/26224377
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201503978
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