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Following the Reaction of Heteroanions inside a {W(18)O(56)} Polyoxometalate Nanocage by NMR Spectroscopy and Mass Spectrometry**
By incorporating phosphorus(III)-based anions into a polyoxometalate cage, a new type of tungsten-based unconventional Dawson-like cluster, [W(18)O(56)(HP(III)O(3))(2)(H(2)O)(2)](8−), was isolated, in which the reaction of the two phosphite anions [HPO(3)](2−) within the {W(18)O(56)} cage could be f...
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| 出版年: | Angew Chem Int Ed Engl |
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| 主要な著者: | , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
WILEY-VCH Verlag
2015
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4557056/ https://ncbi.nlm.nih.gov/pubmed/26013548 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201502295 |
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