Following the Reaction of Heteroanions inside a {W(18)O(56)} Polyoxometalate Nanocage by NMR Spectroscopy and Mass Spectrometry**

By incorporating phosphorus(III)-based anions into a polyoxometalate cage, a new type of tungsten-based unconventional Dawson-like cluster, [W(18)O(56)(HP(III)O(3))(2)(H(2)O)(2)](8−), was isolated, in which the reaction of the two phosphite anions [HPO(3)](2−) within the {W(18)O(56)} cage could be f...

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Detalles Bibliográficos
Publicado en:Angew Chem Int Ed Engl
Main Authors: Zheng, Qi, Vilà-Nadal, Laia, Busche, Christoph, Mathieson, Jennifer S, Long, De-Liang, Cronin, Leroy
Formato: Artigo
Idioma:Inglês
Publicado: WILEY-VCH Verlag 2015
Assuntos:
Communications
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4557056/
https://ncbi.nlm.nih.gov/pubmed/26013548
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201502295
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