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P–C-Activated Bimetallic Rhodium Xantphos Complexes: Formation and Catalytic Dehydrocoupling of Amine–Boranes**
{Rh(xantphos)}-based phosphido dimers form by P–C activation of xantphos (4,5-bis(diphenylphosphino)-9,9-dimethylxanthene) in the presence of amine–boranes. These dimers are active dehydrocoupling catalysts, forming polymeric [H(2)BNMeH](n) from H(3)B⋅NMeH(2) and dimeric [H(2)BNMe(2)](2) from H(3)B⋅...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
WILEY-VCH Verlag
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4557049/ https://ncbi.nlm.nih.gov/pubmed/26140498 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201504073 |
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