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Generalized Vibrational Perturbation Theory for Rotovibrational Energies of Linear, Symmetric and Asymmetric Tops: Theory, Approximations, and Automated Approaches to Deal with Medium-to-Large Molecular Systems

Models going beyond the rigid-rotor and the harmonic oscillator levels are mandatory for providing accurate theoretical predictions for several spectroscopic properties. Different strategies have been devised for this purpose. Among them, the treatment by perturbation theory of the molecular Hamilto...

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Detalhes bibliográficos
Publicado no:Int J Quantum Chem
Main Authors: Piccardo, Matteo, Bloino, Julien, Barone, Vincenzo
Formato: Artigo
Idioma:Inglês
Publicado em: Blackwell Publishing Ltd 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4553754/
https://ncbi.nlm.nih.gov/pubmed/26345131
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/qua.24931
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