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Macromolecular Design via an Organocatalytic, Monomer-Specific and Temperature-Dependent “On/Off Switch”. High Precision Synthesis of Polyester/Polycarbonate Multiblock Copolymers
[Image: see text] The employment of a monomer-specific “on/off switch” was used to synthesize a nine-block copolymer with a predetermined molecular weight and narrow distribution (Đ = 1.26) in only 2.5 h. The monomers consisted of a six-membered cyclic carbonate (i.e., 2-allyloxymethyl-2-ethyl-trime...
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| Publicado en: | Macromolecules |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
American Chemical Society
2015
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| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4535708/ https://ncbi.nlm.nih.gov/pubmed/26294800 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.macromol.5b00254 |
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