On the Question of Site-Selective Ligand Exchange in Carboxylate-Substituted Metal Oxo Clusters

Reaction of [Ti(4)Zr(4)O(6)(OBu)(4)(OMc)(16)] (OMc = methacrylate) with acetylacetone (acacH) resulted in dissection of the cluster and formation of [Ti(OBu)(2)(acac)(2)] and the smaller cluster [Ti(2)Zr(4)O(4)(OMc)(16)]. In contrast, the same reaction with [Zr(6)O(4)(OH)(4)(OOCR)(12)](2)·6RCOOH (R...

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Detalhes bibliográficos
Publicado no:Eur J Inorg Chem
Main Authors: Kreutzer, Johannes, Czakler, Matthias, Puchberger, Michael, Pittenauer, Ernst, Schubert, Ulrich
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2015
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4535662/
https://ncbi.nlm.nih.gov/pubmed/26300687
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201500193
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