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Gadolinium-Catalyzed Regio-, and Enantioselective Aminolysis of Aromatic trans-2,3-Epoxy Sulfonamides
The first enantioselective aminolysis of aromatic trans-2,3-epoxy sulfonamides has been accomplished, which was efficiently catalyzed by a Gd-N,N′-dioxide complex. Under the directing effect of the sulfonamide-moiety the ring-opening reaction proceeded selectively at the C-3 position in highly enant...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4526255/ https://ncbi.nlm.nih.gov/pubmed/26058560 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201503391 |
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