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Ru-Catalyzed Isomerization Provides Access to Alternating Copolymers via Ring-Opening Metathesis Polymerization

[Image: see text] We describe an isomerization–alternating ROMP protocol that gives linear copolymers with rigorous sequence alternation. Bicyclo[4.2.0]oct-7-ene-7-carboxamides of primary amines are isomerized in the presence of (3-BrPyr)(2)Cl(2)(H(2)IMes)Ru=CHPh to the corresponding bicyclo[4.2.0]o...

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Detalhes bibliográficos
Publicado no:Macromolecules
Main Authors: Tan, Li, Li, Guofang, Parker, Kathlyn A., Sampson, Nicole S.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2015
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4520717/
https://ncbi.nlm.nih.gov/pubmed/26243969
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.macromol.5b01058
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