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Uphill diffusion and overshooting in the adsorption of binary mixtures in nanoporous solids

Under certain conditions, during binary mixture adsorption in nanoporous hosts, the concentration of one component may temporarily exceed its equilibrium value. This implies that, in contrast to Fick's Law, molecules must diffuse in the direction of increasing rather than decreasing concentrati...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Lauerer, Alexander, Binder, Tomas, Chmelik, Christian, Miersemann, Erich, Haase, Jürgen, Ruthven, Douglas M., Kärger, Jörg
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Pub. Group 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4518250/
https://ncbi.nlm.nih.gov/pubmed/26177626
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms8697
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