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An Inverted-Sandwich Diuranium μ-η(5):η(5)-Cyclo-P(5) Complex Supported by U-P(5) δ-Bonding**
Reaction of [U(Tren(TIPS))] [1, Tren(TIPS)=N(CH(2)CH(2)NSiiPr(3))(3)] with 0.25 equivalents of P(4) reproducibly affords the unprecedented actinide inverted sandwich cyclo-P(5) complex [{U(Tren(TIPS))}(2)(μ-η(5):η(5)-cyclo-P(5))] (2). All prior examples of cyclo-P(5) are stabilized by d-block metals...
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| Pubblicato in: | Angew Chem Int Ed Engl |
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| Autori principali: | , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
WILEY-VCH Verlag
2015
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4517156/ https://ncbi.nlm.nih.gov/pubmed/25914060 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201501728 |
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