Exploiting the Brønsted Acidity of Phosphinecarboxamides for the Synthesis of New Phosphides and Phosphines

We demonstrate that the synthesis of new N-functionalized phosphinecarboxamides is possible by reaction of primary and secondary amines with PCO(−) in the presence of a proton source. These reactions proceed with varying degrees of success, and although primary amines generally afford the correspond...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Veröffentlicht in:Chemistry
Hauptverfasser: Jupp, Andrew R, Trott, Gemma, Payen de la Garanderie, Éléonore, Holl, James D G, Carmichael, Duncan, Goicoechea, Jose M
Format: Artigo
Sprache:Inglês
Veröffentlicht: WILEY-VCH Verlag 2015
Schlagworte:
Communications
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4515089/
https://ncbi.nlm.nih.gov/pubmed/25892576
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201501174
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