Photochemistry of Ru(II) 4,4′-Bi-1,2,3-triazolyl (btz) Complexes: Crystallographic Characterization of the Photoreactive Ligand-Loss Intermediate trans-[Ru(bpy)(κ(2)-btz)(κ(1)-btz)(NCMe)](2+)

We report the unprecedented observation and unequivocal crystallographic characterization of the meta-stable ligand loss intermediate solvento complex trans-[Ru(bpy)(κ(2)-btz)(κ(1)-btz)(NCMe)](2+) (1 a) that contains a monodentate chelate ligand. This and analogous complexes can be observed during t...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Welby, Christine E, Armitage, Georgina K, Bartley, Harry, Wilkinson, Aaron, Sinopoli, Alessandro, Uppal, Baljinder S, Rice, Craig R, Elliott, Paul I P
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2014
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Full Papers
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4506527/
https://ncbi.nlm.nih.gov/pubmed/24889966
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201402354
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