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Kinetics of the [4+2] cycloaddition of cyclopentadiene with (E)-2-aryl-1-cyano-1-nitroethenes

ABSTRACT: The electrophilicity of (E)-2-aryl-1-cyano-1-nitroethenes is not sufficient to induce a zwitterionic course of their [4+2] cycloaddition to cyclopentadiene. The one-step mechanism of these reactions is indicated by the activation parameters, and the substituent and solvent effects on the r...

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Detalhes bibliográficos
Publicado no:Monatsh Chem
Main Authors: Jasiński, Radomir, Kwiatkowska, Magdalena, Barański, Andrzej
Formato: Artigo
Idioma:Inglês
Publicado em: Springer Vienna 2012
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4495029/
https://ncbi.nlm.nih.gov/pubmed/26166865
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00706-012-0735-3
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