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Nitroacetylene as dipolarophile in [2 + 3] cycloaddition reactions with allenyl-type three-atom components: DFT computational study

ABSTRACT: [2 + 3] Cycloaddition reactions of nitroacetylene with allenyl-type three-atom components take place according to the polar, but a one-step mechanism. Alternatively to cycloadducts, during the reaction between the aforementioned reagents, zwitterionic structures with “extended” conformatio...

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Shranjeno v:
Bibliografske podrobnosti
izdano v:Monatsh Chem
Glavni avtor: Jasiński, Radomir
Format: Artigo
Jezik:Inglês
Izdano: Springer Vienna 2015
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4495019/
https://ncbi.nlm.nih.gov/pubmed/26166899
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00706-014-1389-0
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