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Synthesis of Polycyclic Nitrogen Heterocycles via Cascade Pd-Catalyzed Alkene Carboamination/Diels-Alder Reactions

[Image: see text] Cascade Pd-catalyzed alkene carboamination/Diels-alder reactions between bromodienes and amines bearing two pendant alkenes are described. These transformations generate 4 bonds, three rings, and 3–5 stereocenters to afford polycyclic nitrogen heterocycles with high diastereoselect...

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Bibliographic Details
Published in:Org Lett
Main Authors: White, Derick R., Wolfe, John P.
Format: Artigo
Language:Inglês
Published: 2015
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4480637/
https://ncbi.nlm.nih.gov/pubmed/25946563
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b00896
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