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Quantum tunneling observed without its characteristic large kinetic isotope effects
Classical transition-state theory is fundamental to describing chemical kinetics; however, quantum tunneling is also important in explaining the unexpectedly large reaction efficiencies observed in many chemical systems. Tunneling is often indicated by anomalously large kinetic isotope effects (KIEs...
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| Vydáno v: | Proc Natl Acad Sci U S A |
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| Hlavní autoři: | , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
National Academy of Sciences
2015
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4475983/ https://ncbi.nlm.nih.gov/pubmed/26034285 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1501328112 |
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