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Single-Electron Transmetalation: An Enabling Technology for Secondary Alkylboron Cross-Coupling
Single-electron-mediated alkyl transfer affords a novel mechanism for transmetalation, enabling cross-coupling under mild conditions. Here, general conditions are reported for cross-coupling of secondary alkyltrifluoroborates with an array of aryl bromides mediated by an Ir photoredox catalyst and a...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4466116/ https://ncbi.nlm.nih.gov/pubmed/25650892 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja512946e |
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