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Crystal structure of μ-cyanido-1:2κ(2) N:C-dicyanido-1κC,2κC-bis(quinolin-8-amine-1κ(2) N,N′)-2-silver(I)-1-silver(II): rare occurrence of a mixed-valence Ag(I,II) compound
The title dinuclear complex, [Ag(2)(CN)(3)(C(9)H(8)N(2))(2)], may be considered as an Ag(II) compound with the corresponding metal site coordinated by two bidentate quinolin-8-amine molecules, one cyanide group and one dicyanidoargentate(I) anion, [Ag(CN)(2)](−). Since this latter ligand contains a...
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| Publicat a: | Acta Crystallogr E Crystallogr Commun |
|---|---|
| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
International Union of Crystallography
2015
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4459308/ https://ncbi.nlm.nih.gov/pubmed/26090154 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989015009664 |
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