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Tandem rhodium catalysis:Exploiting sulfoxides for asymmetric transition-metal catalysis
Sulfoxides are uncommon substrates for transition-metal catalysis due to their propensity to inhibit catalyst turnover. In a collaborative effort with Ken Houk, we developed the first dynamic kinetic resolution (DKR) of allylic sulfoxides using asymmetric rhodium-catalyzed hydrogenation. Detailed me...
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| Publicado no: | Org Biomol Chem |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4455901/ https://ncbi.nlm.nih.gov/pubmed/25940066 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5ob00083a |
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