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Crystal structure of μ-oxido-1,1′κ(2) O:O-bis{tetra-μ-oxido-1:2κ(2) O:O;1:3κ(2) O:O;2:3κ(4) O:O-tris[1,2,3(η(5))-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}
The title polynuclear organometallic titanium(IV) oxide, [{Ti(3)(η(5)-C(5)Me(5))(3)(μ-O)(4)}(2)(μ-O)], exhibits two Ti(3)O(4) cores bridged by an O atom located on a twofold axis. All metal centres present the typical three-legged piano-stool coordination environment, where one site is occupied by a...
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| Veröffentlicht in: | Acta Crystallogr E Crystallogr Commun |
|---|---|
| Hauptverfasser: | , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
International Union of Crystallography
2015
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4438812/ https://ncbi.nlm.nih.gov/pubmed/26029420 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989015004041 |
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