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Crystal structures of 1-(4-chlorophenyl)-2-(diphenylphosphoryl)ethan-1-one and 1-(diphenylphosphoryl)-3,3-dimethylbutan-2-one
The title compounds, C(20)H(16)ClO(2)P, (I), and C(18)H(21)O(2)P, (II), were synthesized via an Arbuzov reaction between an α-bromoketone and isopropoxydiphenylphosphane. In the crystals of both compounds, molecules are linked via bifurcated C—H⋯(O,O) hydrogen bonds, forming chains propagating a...
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| Veröffentlicht in: | Acta Crystallogr E Crystallogr Commun |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
International Union of Crystallography
2015
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4420131/ https://ncbi.nlm.nih.gov/pubmed/25995871 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989015006994 |
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